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Transformation of multifunctional materials with control over site-selectivity and chemical diversity remains challenging. Herein, we present a metal-free, one-pot strategy for the defluorophosphorylation of polyfluoroalkyl peroxides that enables expedient construction of structurally diverse phosphoryl-containing heterocyclic libraries. By judicious choice of reaction conditions, C 3,4-diphosphoryl furans and C 4-monophosphoryl furans can be easily accessed. In addition, synthetic derivatization of the obtained organophosphorus heteroarenes to value-added monodentate and bidentate phosphines has been demonstrated. Mechanistic studies revealed that regioselective defluorophosphorylation allows divergent product formation in two reaction modes.more » « less
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Weinberg, Charles; Abel, Julianna; Cai, Song; Schaffer, Jeremy (, Proc. SPIE 11588, Active and Passive Smart Structures and Integrated Systems XV)Han, Jae-Hung; Shahab, Shima; Wang, Gang (Ed.)
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Weinberg, Charles A.; Cai, Song; Schaffer, Jeremy; Abel, Julianna (, Shape Memory and Superelasticity)
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